Common shared system model for evolvable assembly systems

A vital aspect of distributed control in an adaptable production system is coherence between each system resource. The Evolvable Assembly Systems project addresses this challenge using a common shared system model. This paper provides an overview of the project and the shared system model approach as implemented in a real world demonstration cell

Conceptual framework for ubiquitous cyber-physical assembly systems in airframe assembly

Current sectoral drivers for the manufacturing of complex products - such as airframe assembly -require new manufacturing system paradigms to meet them. In this paper, we propose a conceptual framework for cyber-physical systems driven by ubiquitous context-awareness by drawing together a unique and coherent vision that merges several extant concepts. This framework leverages recent progress in agent-based systems, exible manufacturing, ubiquitous computing, and metrology-driven robotic assembly in the Evolvable Assembly Systems project. As such, although it is adapted for and grounded in manufacturing facilities for airframe assembly, it is not specifically tailored to that application and is a much more general framework. As well as outlining our conceptual framework, we also provide a vision for assembly grounded in a review of existing research in the area

Computation with photochromic memory

Unconventional computing is an area of research in which novel materials and paradigms are utilised to implement computation and data storage. This includes attempts to embed computation into biological systems, which could allow the observation and modification of living processes. This thesis explores the storage and computational capabilities of a biocompatible light-sensitive (photochromic) molecular switch (NitroBIPS) that has the potential to be embedded into both natural and synthetic biological systems. To achieve this, NitroBIPS was embedded in a (PDMS) polymer matrix and an optomechanical setup was built in order to expose the sample to optical stimulation and record fluorescent emission. NitroBIPS has two stable forms - one fluorescent and one non-fluorescent - and can be switched between the two via illumination with ultraviolet or visible light. By exposing NitroBIPS samples to specific stimulus pulse sequences and recording the intensity of fluorescence emission, data could be stored in registers and logic gates and circuits implemented. In addition, by moving the area of illumination, sub-regions of the sample could be addressed. This enabled parallel registers, Turing machine tapes and elementary cellular automata to be implemented. It has been demonstrated, therefore, that photochromic molecular memory can be used to implement conventional universal computation in an unconventional manner. Furthermore, because registers, Turing machine tapes, logic gates, logic circuits and elementary cellular automata all utilise the same samples and same hardware, it has been shown that photochromic computational devices can be dynamically repurposed. NitroBIPS and related molecules have been shown elsewhere to be capable of modifying many biological processes. This includes inhibiting protein binding, perturbing lipid membranes and binding to DNA in a manner that is dependent on the molecule's form. The implementation of universal computation demonstrated in this thesis could, therefore, be used in combination with these biological manipulations as key components within synthetic biology systems or in order to monitor and control natural biological processes

C–F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene

The N-heterocyclic carbene IBioxMe4 enacts selective single and double C–F bond activation of octafluorotoluene and hexafluorobenzene, respectively. The formation of the fluoroarene substituted, zwitterionic imidazoliumolate products is consistent with a mechanism involving nucleophilic aromatic substitution and subsequent oxazoline ring opening by liberated fluoride

Computation with photochromic memory

Unconventional computing is an area of research in which novel materials and paradigms are utilised to implement computation and data storage. This includes attempts to embed computation into biological systems, which could allow the observation and modification of living processes. This thesis explores the storage and computational capabilities of a biocompatible light-sensitive (photochromic) molecular switch (NitroBIPS) that has the potential to be embedded into both natural and synthetic biological systems. To achieve this, NitroBIPS was embedded in a (PDMS) polymer matrix and an optomechanical setup was built in order to expose the sample to optical stimulation and record fluorescent emission. NitroBIPS has two stable forms - one fluorescent and one non-fluorescent - and can be switched between the two via illumination with ultraviolet or visible light. By exposing NitroBIPS samples to specific stimulus pulse sequences and recording the intensity of fluorescence emission, data could be stored in registers and logic gates and circuits implemented. In addition, by moving the area of illumination, sub-regions of the sample could be addressed. This enabled parallel registers, Turing machine tapes and elementary cellular automata to be implemented. It has been demonstrated, therefore, that photochromic molecular memory can be used to implement conventional universal computation in an unconventional manner. Furthermore, because registers, Turing machine tapes, logic gates, logic circuits and elementary cellular automata all utilise the same samples and same hardware, it has been shown that photochromic computational devices can be dynamically repurposed. NitroBIPS and related molecules have been shown elsewhere to be capable of modifying many biological processes. This includes inhibiting protein binding, perturbing lipid membranes and binding to DNA in a manner that is dependent on the molecule's form. The implementation of universal computation demonstrated in this thesis could, therefore, be used in combination with these biological manipulations as key components within synthetic biology systems or in order to monitor and control natural biological processes

UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex

Iridium(I) carbonyl complex [Ir(2,6-(PtBu2CH2)2C6H3)(CO)] undergoes reversible C–H bond activation of benzene and a series of fluorobenzenes on UV irradiation. Exclusive ortho-selectivity is observed in reactions of fluorobenzene and 1,2-difluorobenzene

Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand

The synthesis and solid-state characterisation of the heterobimetallic rhodium(III)/silver(I) complex [Rh(2,2’‑biphenyl)(CxP2)Cl]⊃Ag+ is described, where CxP2 is a trans-spanning calix[4]arene-based diphosphine and the silver cation is datively bound to the chloride ligand within the cavity of the macrocycle

Common shared system model for evolvable assembly systems

A vital aspect of distributed control in an adaptable production system is coherence between each system resource. The Evolvable Assembly Systems project addresses this challenge using a common shared system model. This paper provides an overview of the project and the shared system model approach as implemented in a real world demonstration cell

Realisability of production recipes

There is a rising demand for customised products with a high degree of complexity. To meet these demands, manufacturing lines are increasingly becoming autonomous, networked, and intelligent, with production lines being virtualised into a manufacturing cloud, and advertised either internally to a company, or externally in a public cloud. In this paper, we present a novel approach to two key problems in such future manufacturing systems: the realisability problem (whether a product can be manufactured by a set of manufacturing resources) and the control problem (how a particular product should be manufactured). We show how both production recipes specifying the steps necessary to manufacture a particular product, and manufacturing resources and their topology can be formalised as labelled transition systems, and define a novel simulation relation which captures what it means for a recipe to be realisable on a production topology. We show how a controller that can orchestrate the resources in order to manufacture the product on the topology can be extracted from the simulation relation, and give an algorithm to compute a simulation relation and a controller